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CD1 – Big Brother & the Holding Company
1.“Bye, Bye Baby” Powell St. John 2:37
2.“Easy Rider” James Gurley 2:23
3.“Intruder” Janis Joplin 2:27
4.“Light Is Faster Than Sound” Peter Albin 2:30
5.“Call on Me” Sam Andrew 2:32
6.“Women Is Losers” Joplin 2:03
7.“Blindman” Albin, Andrew, David Getz, Gurley, Joplin 2:23
8.“Down on Me“ Traditional, arr. Joplin 2:04
9.“Caterpillar” Albin 2:18
10.“All Is Loneliness” Moondog 2:30
11. Coo Coo (Single)
12. The Last Time
13. Call On Me (Alt. Take)
14. Bye, Bye, Baby (Alt. Take)

CD2 – Cheap Thrills
1. “Combination of the Two” Sam Andrew 5:47
2. “I Need a Man to Love” Andrew, Janis Joplin 4:54
3. “Summertime“ George Gershwin, Ira Gershwin, DuBose Heyward 4:01
4. “Piece of My Heart“ Bert Berns, Jerry Ragovoy 4:15
5. “Turtle Blues” Joplin 4:22
6. “Oh, Sweet Mary” Peter Albin, Andrew, David Getz, James Gurley, Joplin 4:16
7. “Ball and Chain“ Big Mama Thornton 9:02
8. “Roadblock” (Studio outtake) 5:31
9. “Flower in the Sun” (Studio outtake) Sam Andrew 3:04
10. “Catch Me Daddy” (Live at The Grande Ballroom, Detroit, MI, March 2, 1968) 5:32
11. “Magic of Love” (Live at The Grande Ballroom, Detroit, MI, March 2, 1968)

CD3 – I Got Dem Ol’ Kozmic Blues Again Mama!
1. “Try (Just a Little Bit Harder)” Jerry Ragovoy, Chip Taylor 3:57
2. “Maybe“ Richard Barrett 3:41
3. “One Good Man” Janis Joplin 4:12
4. “As Good As You’ve Been to This World” Nick Gravenites 5:27
5. “To Love Somebody“ Barry Gibb, Robin Gibb 5:14
6. “Kozmic Blues“ Joplin, Gabriel Mekler 4:24
7. “Little Girl Blue“ Lorenz Hart, Richard Rodgers 3:51
8. “Work Me, Lord” Nick Gravenites 6:45
9. “Dear Landlord” (Session Outtake 6.17.69) Bob Dylan, Joplin 2:32
10. “Summertime” (Live at Woodstock, August 1969) George Gershwin 5:04
11. “Piece of My Heart” (Live at Woodstock, August 1969) Ragovoy, Bert Berns

CD4 – Pearl
1. “Move Over” Janis Joplin 3:39
2. “Cry Baby“ Jerry Ragovoy, Bert Berns 3:55
3. “A Woman Left Lonely” Dan Penn, Spooner Oldham 3:27
4. “Half Moon” John Hall, Johanna Hall 3:51
5. “Buried Alive in the Blues” Nick Gravenites 2:24
6. “My Baby” Jerry Ragovoy, Mort Shuman 3:44
7. “Me and Bobby McGee“ Kris Kristofferson, Fred Foster 4:29
8. “Mercedes Benz“ Janis Joplin, Bob Neuwirth, Michael McClure 1:46
9. “Trust Me” Bobby Womack 3:15
10. “Get It While You Can” Jerry Ragovoy, Mort Shuman (Howard Tate 1966 rendition) 3:23
11. “Tell Mama” (Festival Express Tour, July 4, 1970) Clarence Carter, Marcus Daniel, Wilbur Terrell 6:32
12. “Little Girl Blue” (Festival Express Tour, July 4, 1970) Richard Rodgers, Lorenz Hart 3:50
13. “Try (Just a Little Bit Harder)” (Festival Express Tour, July 4, 1970) Jerry Ragovoy, Chip Taylor 6:52
14. “Cry Baby” (Festival Express Tour, July 4, 1970) Jerry Ragovoy, Bert Berns 6:29

CD5 – Rare Pearls
1. “It’s a Deal” (Studio Outtake) 2:18
2. “Easy Once You Know How” (Studio Outtake) 3:53
3. “Maybe” (Live) 4:01
4. “Raise Your Hand” (Live) 5:16
5. “Bo Diddley” (Live) 6:13